Photographic industry use it as a photo sensitizer. Cleanrooms or other controlled environments used for research or manufacturing need specialized products. + 3S? Avantor supports end-to-end fluid management solutions including Masterflex peristaltic pumps and aseptic fluid transfer solutions that are reliable and customer-centric, helping bioprocessing manufacturers meet their research and production goals. Synonym. Lead II Nitrate formula, also known as Lead nitrate formula or Lead dinitrate formula is explained in this article. Lead sulfide ore is taken as raw material and subject to reaction with nitric acid under certain conditions to obtain the lead nitrate solution containing Zn2 +, Fe3 +, Cu2 + and other impurities. [28] Lead is known to substitute for zinc in a number of enzymes, including -aminolevulinic acid dehydratase (porphobilinogen synthase) in the haem biosynthetic pathway and pyrimidine-5-nucleotidase, important for the correct metabolism of DNA and can therefore cause fetal damage. MDL Number. This is potentially due to a lead lone pair of electrons, also found in lead complexes with an imidazole ligand.[13]. ACS, REAG. During the operation, the worker should wear masks. You can select and customize services for peak efficiency, quality, and accelerated innovation. 5Pb(OH)2 is formed. Lead oxide can be used in flash powders, but this is rarely done, as the combustion releases airborne particles of toxic lead oxide. Shelf Life: 36 Months. Avantor is now supporting customers active in research & development, production and recycling of advanced batteries. (3). Supplier: Thermo Scientific Chemicals. Best Answer. direct synthesis method using lead ore Explanation: You're . Historical compounds, such as Muriatic acid, MSDS for lead nitrate, Mallinckrodt/J.T.Baker, MSDS for lead nitrate, PTCL, Oxford University, MSDS for lead nitrate, Iowa State University. As your trusted, collaborative partner, Avantor Services helps you increase efficiency, maximize productivity, and accelerate innovation. the ions that are present on both sides of the equation, will look like this, #"Pb"_text((aq])^(2+) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-)))) + color(red)(cancel(color(black)(color(red)(2)"Na"_text((aq])^(+)))) + color(red)(2)"I"_text((aq])^(-) -> "PbI"_text(2(s]) darr + color(red)(cancel(color(black)(color(red)(2)"Na"_text((aq])^(+)))) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-))))#, #"Pb"_text((aq])^(2+) + color(red)(2)"I"_text((aq])^(-) -> "PbI"_text(2(s]) darr#. Special instructions for handling are included in all Material Safety Data Sheets (MSDS). Explosive hazardous properties it is explosive when being mixed, heated, impacted and rubbed by reducing agent, sulfur and phosphorus. [5] It is produced commercially by reaction of metallic lead with concentrated nitric acid in which it is sparingly soluble. Lead metal, however, is easily obtainable and can be used to produce it if nitric acid is available. VWR will not lift restrictions for residential shipping addresses. Click the answer you think is right. At higher pH Pb6(OH)5(NO3) is formed. Life Science Research Solutions, Products, and Resources, How to Select the Right Chromatography Resin, Thermo Scientific Chromatography Columns and Consumables, Liquid Chromatography - Sample Preparation, Biopharma production chemicals & excipients, Laboratory Personal Protection Equipment (PPE) and Workwear Products, Laboratory Facilities Maintenance, Protection, and Hygiene Supplies, Building a Safe Work Environment with VWR, Rheo Flexibles: Single-Use Containment and Transfer Technology, Aerospace & Automotive Industry Cleanroom Products, Pharmaceuticals, Biotechnology and Nutraceuticals, Micronova - Contamination Control Made Simpler, Masterflex Peristaltic Pump and Fluid Handling Solutions, Quality Products from Sheldon Manufacturing, Lab Thermometers & Temperature Measurement Equipment, Agilent Chemistries and Supplies Portfolio, PerkinElmer - Innovating for a Healthier World, Sartorius laboratory instruments, consumables and services, HALO Chromatography Columns and Consumables+-, The Avantor Value as a Medical Lab Partner, Reference materials Laboratory Products, Specialized Solutions for Cutting Applications, Contact Your Laboratory Furniture Specialist. total units of the original product. You need to be comfortable and find the proper fit, VWR wants to help find the best pipette for you. P201-P202-P210-P220-P221-P260-P264b-P270-P271-P281-P301+P312-P304+P340-P305+P351+P338-P308+P313-P310-P330-P370+P378q-P501c, H272-H302+H332-H318-H336-H350-H360Df-H373, DOTInformation : Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: LEAD NITRATE, Recommended Storage : Ambient temperatures, lead dinitrate, lead nitrate, lead ii nitrate, plumbous nitrate, lead 2+ nitrate, lead nitrate pb no3 2, nitrate de plomb french, lead ii nitrate 1:2, nitric acid, lead 2+ salt, [N+](=O)([O-])[O-].[N+](=O)([O-])[O-]. Moderately toxic by ingestion and other routes of exposure. When the salt is carefully dried, and heated in a steel vessel, it produces nitrogen dioxide along with dioxygen. It acts as a scavenger of bromide in nucleophilic substitution reactions. Explore our solutions for multiple applications - vaccines, monoclonal antibodies, recombinant proteins, cell or gene therapy. Avantor supports end-to-end fluid management solutions including peristaltic pumps and aseptic fluid transfer solutions that are reliable and customer-centric, helping bioprocessing manufacturers meet their research and production goals. Ph Eur. Use the crisscross method to check your work.Notes:- Dont write the subscript '1'.- If you use the criss-cross method and end up with something like Ca2S2 you'll need to reduce the subscripts to Ca1S1 which we write CaS.- It is possible to have two polyatomic ions such as NH4NO3. After cultivation of mung bean seedlings for five days, the half-inhibitory concentration (IC50) of leaf and root of the lead nitrate of mung bean seedlings were 276.33 and 6.47 mg/L, respectively. However it is somewhat sensitive to water over time, so it's best to store it in a dry sealed container. To add items to your cart, enter a quantity and click Add to Cart. Toxicity classification highly toxic The VWR Traceable Logger-Trac Temperature Datalogger is perfect for monitoring material during storage, handling, and transportation. Life Science Research Solutions, Products, and Resources, How to Select the Right Chromatography Resin, Thermo Scientific Chromatography Columns and Consumables, Liquid Chromatography - Sample Preparation, Biopharma production chemicals & excipients, Laboratory Personal Protection Equipment (PPE) and Workwear Products, Laboratory Facilities Maintenance, Protection, and Hygiene Supplies, Building a Safe Work Environment with VWR, Rheo Flexibles: Single-Use Containment and Transfer Technology, Aerospace & Automotive Industry Cleanroom Products, Pharmaceuticals, Biotechnology and Nutraceuticals, Micronova - Contamination Control Made Simpler, Masterflex Peristaltic Pump and Fluid Handling Solutions, Quality Products from Sheldon Manufacturing, Lab Thermometers & Temperature Measurement Equipment, Agilent Chemistries and Supplies Portfolio, PerkinElmer - Innovating for a Healthier World, Sartorius laboratory instruments, consumables and services, HALO Chromatography Columns and Consumables+-, The Avantor Value as a Medical Lab Partner, Reference materials Laboratory Products, Specialized Solutions for Cutting Applications, Contact Your Laboratory Furniture Specialist, State issued document with your organization's Federal Tax ID Number, State issued document with your organization's Resale Tax ID Number, State Department of Health Services License, Any other ID issued by the State that includes the business name & address. The compound can be obtained by dissolving metallic lead in aqueous nitric acid: More commonly, lead(II) nitrate is obtained by dissolving lead oxide, which is readily available as a mineral, in aqueous nitric acid:[15]. We continue to set science in motion to create a better world by providing you with the right solutions to keep moving forward. The lead (II) ion is represented as Pb2+, whilst the nitrate ion is NO 3. Basic nitrates are formed in when alkali is added to a solution. In this configuration, every lead atom is bonded to twelve oxygen atoms (bond length: 281pm). Mineral powder can have reaction after coming across acid, the main reaction occurs as follows: LEAD ION CHROMATOGRAPHY STANDARD SOL. It is utilized to improve the leaching process in the gold cyanidation. Toxicity of lead nitrate on the mung bean seedlings Synonyms: Lead dinitrate. ; weakness, which may go on to paralysis, chiefly of the extensor muscles of the wrists and less often the ankles, is noticeable in the most serious cases. Our portfolio is used in virtually every stage of the most important research, development and production activities in the industries we serve. It can be mixed with flammable or fine powder to form an explosive mixture. The lead nitrate appears as a white cubic crystal or monoclinic crystalline powder. Historically, the main use was as a raw material in the production of pigments for lead paints, but such paints have been superseded by less toxic paints based on titanium dioxide. at 20 C). Lead nitrate was first identified in 1597 by the alchemist Andreas Libavius, who called the substance plumbum dulce, meaning "sweet lead", because of its taste. [27] They have been linked to renal cancer and glioma in experimental animals and to renal cancer, brain cancer and lung cancer in humans, although studies of workers exposed to lead are often complicated by concurrent exposure to arsenic. 5 year bumper to bumper warranty! 4. Thermal decomposition of lead (ll) nitrate; Take 1g of lead (ll) nitrate in the test tube and heat the test tube on the Bunsen burner flame, holding the test tube in the slanting position. Avantor Services provides a wide range of specialized services and digital solutions to help you solve complex challenges. [CDATA[ Carry out the replacement reaction for cooper removal at the condition of around 50.At this time, the solubility of the nitrate lead is 44% while the cooper content in the lead nitrate solution is about 0.025%. How is savings calculated?We All rights reserved. VWR will support you from the latest life science products to the guaranteed purity of organic building blocks VWR is ready to support your production facility with reliable access to raw materials and essential supplies. The crystal structure of solid lead(II) nitrate has been determined by neutron diffraction. Previous question Next question. Easy access to products and protocols for research use only in the identification of 2019-nCoV based on Centers for Disease Control and Prevention (CDC) recommendations. Avantor , a Fortune 500 company, is a leading global provider of mission-critical products and services to customers in the biopharma, healthcare, education & government, and advanced technologies & applied materials industries.Our portfolio is used in virtually every stage of the most important research, development and production activities in the industries we serve. 1. hydrolysis for iron removal Lead(II) nitrate is an inorganic compound with the chemical formula Pb(NO 3) 2.It is a colourless crystal or white powder and, unlike most other lead(II) salts, it is soluble in water.Known since the Middle Ages by the name plumb dulcis, its main use has been as raw material in the production of pigments in lead paints.Lead(II) nitrate production from either metallic lead or lead oxide in . FeS + 4HNO3 = Fe (NO3) 3 + NO + S + 2H2O Products that fall under this regulation will be placed on a mandatory 21-day hold after documentation is received. For example, combining lead nitrate and pentaethylene glycol (EO5) in a solution of acetonitrile and methanol followed by slow evaporation produces a new crystalline material [Pb(NO3)2(EO5)]. As our customers needs have evolved, so have our capabilities. The molecular or chemical formula of Lead II Nitrate is Pb(NO 3) 2.. Lead nitrate is colourless to white crystalline solid which is completely soluble in water but slightly soluble . VAI's cellulose free, low particlate and chemical resistant cleanroom paper. Binders, calendars, pens, cleaning and sanitation supplies, and office equipment are just some of the essential products we offer Science education supplies, specimens, activities, and equipment for all grade levels kindergarten to college. The toxic effects are greater than other lead salts because lead nitrate is more soluble. 49:23. [Pb+2], Except where otherwise noted, data are given for materials in their. Being water-soluble, it is even more so, and should always be handled with gloves and skin protection, and the very strictest of measures should be taken to prevent its ingestion. 2. take the metal lead as raw material, first make crude lead nitrate; after the hydrolysis of iron; apply lead replacement of copper, and then carry re-crystallization to obtain it. Lead (II) nitrate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. 2023 FORTUNE Media IP Limited All rights reserved. Process flow chart is shown in Figure 1 below. RLJMLMKIBZAXJO-UHFFFAOYSA-N Show More. Weigh 0.4000 grams of galena in a dry 300ml beaker, add 15ml hydrochloric acid and steam at low temperature to evaporate 3~5 ml; add 10ml nitric acid-sulfate mixed acid, continue to heat and remove it until it is nearly dry. It is soluble in water, liquid ammonia, slightly soluble in ethanol but insoluble in concentrated nitric acid (generate protective film). Ingestion of a large amount causes local irritation of the alimentary tract; pain, leg cramps, muscle weakness, paresthesias, depression, coma, and death may follow in 1 or 2 days. Avantor supports end-to-end fluid management solutions including Masterflex peristaltic pumps and aseptic fluid transfer solutions that are reliable and customer-centric, helping bioprocessing manufacturers meet their research and production goals. Easy access to products and protocols for research use only in the identification of 2019-nCoV based on Centers for Disease Control and Prevention (CDC) recommendations. For example, when a large number of lead nitrate get fire, nitrate may melt and melt, avoid using water for fire extinguishing to prevent the spray of a large amount of molten lead nitrate. Structure, properties, spectra, suppliers and links for: Lead(II) nitrate, 10099-74-8. The pH value of aqueous solution of crude lead nitrate is 1~2; use ammonia to adjust to until the turbid phenomenon doesnt disappear as more, the pH value at this time is 3~4. Strong oxidizer. For more information, call 1.888.793.2300. It should be stored in a cool dry and ventilated place. Find everything you need to start setting up your lab, including special savings, checklists, and more From scientific discovery to scale-up and commercial delivery, Avantor offers mission-critical products, services and solutions on a global scale. For your security, we have logged you out. There are lead vapor, nitrogen oxide gas and lead nitrate existing during the production process, these substances are toxic so the equipment should be closed and the production environment should be well ventilated. Lead(II) nitrate is toxic and must be handled with care to prevent inhalation, ingestion and skin contact. 3Pb + 8HNO3 = 3Pb (NO3) 2 + 2NO + 4H2O The products you use, the products you need, the suppliers you trust for chromatography. Soluble in water. Note: The chemical specifications for some items on this product page may differ from the specifications listed above. Pb(NO3)2 is limited to the activation of stibnite during beneficiation of antimony ores. Molecular Weight 331.21. Avantor, a Fortune 500 company, is a leading global provider of mission-critical products and services to customers in the biopharma, healthcare, education & government, and advanced technologies & applied materials industries. After slightly cooling, add 4 ml of sulfuric acid (1: 1) and wash the cup wall with distilled water to about 50ml. Exceptional skid resistance, both wet and dry, for dirty jobs and controlled environments. If you need further assistance, please call VWR Customer Service at 1-800-932-5000. Lead nitrate is prone to partial hydrolysis in water, giving neutral solutions a cloudy appearance. Avantor can help maintain cleanroom standards with protective apparel and environmental monitoring equipment. 1.00 G PB, AMPOULE, lead atomic spectroscopy standard concentrate 1.00 g pb, Lead standard solution, for AAS, 1 Mg/Ml Pb in 2 to 5% HNO3, Lead standard solution, 1 mg/ml Pb in 2% HNO3, for AAS, Lead standard solution,for AAS,1 mg/ml Pb in2% HNO3, Lead(II) Nitrate, Puratronic (Metals Basis), Lead(II) nitrate, 99.999%, (trace Metal basis), Lead standard solution, 1 Mg/Ml Pb in 2% HNO3, for AAS 100ML, H272-H302+H332-H317-H318-H360FD-H372-H410, P210-P273-P280-P304+P340+P312-P305+P351+P338-P308+P313, 61-8-20/22-33-50/53-62-52/53-36/38-51/53-35-41-34, LEAD, STANDARD SOLUTION 1000 MG/L PB FOR AA (LEAD(II) NITRATE IN NITRIC ACID 0,5 MOL/L). [20] One interesting aspect of this type of complexes is the presence of a physical gap in the coordination sphere; i.e., the ligands are not placed symmetrically around the metal ion. PBL6360 - LEAD(II) NITRATE LEAD(II) NITRATE Safety Data Sheet PBL6360 Date of issue: 04/01/2016 Version: 1.0 04/01/2016 EN (English US) SDS ID: PBL6360 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Avantor supports end-to-end fluid management solutions including peristaltic pumps and aseptic fluid transfer solutions that are reliable and customer-centric, helping bioprocessing manufacturers meet their research and production goals. VWR is your complete source for workplace supplies. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Lead nitrate decomposes on heating, a property that has been used in pyrotechnics . The Fe3 + should be completely hydrolyzed to form Fe (OH)3 precipitate to be removed. Zn2 + + 2OH-= Zn (OH) 2 Formula: Pb (NO). MW: 331.21 g/mol. Ph Eur. Our solutions, developed with you as our focus, are crafted by our team and network of professionals with advanced degrees in science, quality control, engineering, manufacturing and industry experience. The total coordination number is 10, with the lead ion in a bicapped square antiprism molecular geometry. Lead(II) Nitrate molecular weight Molar mass of Pb(NO3)2 = 331.2098 g/mol It was widely used as a raw material in the manufacturing of pigments for lead paints. Avantor can help equip your life sciences lab with the products, equipment, and supplies you need whether you work in cell biology, genomics, proteomics, or other fields. The nuclear rupture may be due to that the lead nitrate destroy the nuclear pore complex protein. Watch on. This is a white to colorless fine crystalline compound, extremely soluble in water (34% Lead (II) nitrate is an inorganic compound with the chemical formula Pb (NO). Lead Nitrate Crystal ACS Grade. Further use dilute sulfuric acid solution (2%) to wash for 3 to 4 times and finally wash with distilled water for additional 1 to 2 times. Some documentation and label information may refer to the legacy brand. Write the symbol and charge for the non-metal. 1936]. The black dots represent the lead atoms, the white dots the nitrate groups 27picometres above the plane of the lead atoms, and the blue dots the nitrate groups the same distance below this plane. This product has been blocked by your organization. LEAD ATOMIC SPECTROSCOPY STANDARD CONC. LEAD(II) NITRATE R. G., REAG. To compare product details, select up to 3 alternatives below and click Compare Selected. CAS #: 10099-74-8 EC Number: 233-245-9 Molar Mass: 331.2 g/mol Chemical Formula: Pb (NO) Hill Formula: NOPb Grade: ACS,Reag. Please sign in to view account pricing and product availability. Screen capture done with Camtasia Studio 4.0. 2. In nitric acid treatment of lead-containing wastes, e.g., in the processing of lead-bismuth wastes from lead refineries, impure solutions of lead(II) nitrate are formed as by-product. Lead (II) nitrate, Pb (NO3)2 (aq) and sodium sulfate, Na2SO4 (aq) foovan Observations: Molecular Equation: Complete Ionic Equation: Net . It causes an explosion if it is exposed to heat or fire for a long time. It finds applications as a lead paint as well as a source of dinitrogen tetroxide. New Avantor J.T.Baker premium conductive and non-conductive robotic tips deliver superior quality and reliable performance for results you can trust. 5 year bumper to bumper warranty! //]]>. side reaction: When heated, lead(II) nitrate crystals decompose to lead(II) oxide, dioxygen and nitrogen dioxide, accompanied by a crackling noise. Lead nitrate is readily obtained by dissolving metallic lead, lead monoxide, or lead carbonate in dilute nitric acid. PH. The impurity iron in the crude lead nitrate is present as an ionic Fe3 +. [12] One interesting aspect of this type of complexes is the presence of a physical gap in the coordination sphere, i.e., the ligands are not placed symmetrically around the metal ion. 3PbS + 8HN03 = 3Pb (N03) 2 + 3S + 2N0 + 4H2O Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. So much has changed during this unprecedented time, except your ability to count on Avantor. A VWR representative will contact you if needed. Potassium nitrate dissolves in water. Lead nitrate | Pb(NO3)2 or N2O6Pb | CID 24924 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological . Finally, in potassium nitrate, the charges balance in another 1:1 ratio, giving a formula of KNO3 . PbSO4 + Fe = FeSO4 + Pb Avantor helps keep you safe with a robust line of safety products and personal protective equipment -- from waste bins to safety signs. Please contact your purchasing department for more information. Production of lead nitrate with fine ore powder as raw material mineral processing. Lead dinitrate is noncombustible but Lead dinitrate will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in fires involving Lead dinitrate. VAI's cellulose free, low particlate and chemical resistant cleanroom paper. Lead nitrate, like other lead compounds, is highly toxic and is a cumulative poison that accumulates in the body. Lead nitrate is slowly formed by the reaction between nitric acid and lead metal, and can also be produced at a much faster rate and in better yield by dissolving lead oxides or lead hydroxide/carbonate in nitric acid. Avantor can help you plan, design, and configure a custom laboratory environment that meets all your needs. This product is no longer available. Although lead may activate sphalerite, similar to CuSO4, the use of 1997-2023 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Lead%28II%29_nitrate.html, Your browser is not current. High-quality chemicals and services, customized to your product or manufacturing needs VWR enables the advancement of science by providing high-quality chemicals and services, customized to your product or manufacturing needs. Avantor , a Fortune 500 company, is a leading global provider of mission-critical products and services to customers in the biopharma, healthcare, education & government, and advanced technologies & applied materials industries.Our portfolio is used in virtually every stage of the most important research, development and production activities in the industries we serve. [22], Categories: IARC Group 2A carcinogens | Lead compounds | Nitrates. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. The other product of the reaction is aqueous sodium nitrate, #"NaNO"_3#, which will exist as ions in solution. Dependable -80C storage with a focus on sustainability without sacrificing sample protection. Your browser does not support JavaScript. Freeze cells in tubes from 1 to 5mL using the Thermo Scientific Mr. Frosty Freezing Container at nearly -1C/minute. [18] After two recrystallisations of ACS grade, no metals above 0.001ppm were detected. Required fields are marked *. Durable, low-linting, & available in white or blue. Find everything you need to start setting up your lab, including special savings, checklists, and more From scientific discovery to scale-up and commercial delivery, Avantor offers mission-critical products, services and solutions on a global scale. 2. replacement for copper removal The main impurities in crude lead nitrate are iron and copper. Acute toxicity Intraperitoneal-rat LDL0: 270 mg/kg; Abdominal-mouse LD50: 74 mg/kg 260525 views [22][23], In organic chemistry, it may be used in the preparation of isothiocyanates from dithiocarbamates. If the. These gloves offer the perfect combination of improved elongation with outstanding protection from chemotherapy drugs, and an FDA-approved low dermatitis potential claim. The replacement shown is available. Given that lead nitrate is the most commonly encountered water-soluble lead salt, it is an important precursor to other insoluble lead compounds. window.__mirage2 = {petok:"E.rFa_QOwpkb.ENw8kVuOX6GeA74FojFi2r0Epj1GTk-31536000-0"}; Pb (NO3) 2 + K2SO4 = PbSO4 + 2KN03 Solubility of lead nitrate in nitric acid at 26 C. For information visit, www.avantorsciences.com and find us on LinkedIn, Twitter and Facebook. Above 470 C, lead nitrate is decomposed to lead monoxide and Pb3O4. Due to its hazardous nature, the limited applications of lead(II) nitrate are under constant scrutiny. It is an oxidizing agent which is highly toxic and categorized as probably carcinogenic to humans. + 4H2O It should be kept away from food and metal powder. Add 15 mL 10% hexamethylenetetramine solution, 20mL of water and several drops of xylene. Lead(II) nitrate is associated with interesting supramolecular chemistry because of its coordination to nitrogen and oxygen electron-donating compounds. Avantor , a Fortune 500 company, is a leading global provider of mission-critical products and services to customers in the biopharma, healthcare, education & government, and advanced technologies & applied materials industries.Our portfolio is used in virtually every stage of the most important research, development and production activities in the industries we serve. Since Pb(NO3)2 has very low solubility in nitric acid, the lead(II) nitrate is crystallised directly from the solution. At 470 C, it is decomposed into lead oxide, nitrogen dioxide and oxygen. The total coordination number is 10, with the lead ion in a bicapped square antiprism molecular geometry. Lead nitrate is highly soluble in water (56.5 g/100 mL at 20 C; 127 g/100 mL at 100 C), soluble in alkalies and ammonia, and fairly soluble in alcohol (8.77 g/ 100 mL of 43% aqueous ethanol at 22 C).
Accident On Mannheim Road Last Night, What Is Corey Crawford Doing Now, Kashi Strawberry Bars Discontinued, Angela Cartwright Husband, Roy Rogers Daughter Lynda Carter, Articles L